Nitrolysis of 1, 3-6, 8-Diendomethylene-1, 3, 6, 8-tetrazacyclodecane

RJJ Simkins, GF Wright

Index: Simkins; Wright Journal of the American Chemical Society, 1955 , vol. 77, p. 3157

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Citation Number: 19

Abstract

XI of acetic anhydride and 50 ml. of acetic acid was stirred and chilled at 0" while 16.6 ml.(0.40 mole) of absolute nitric acid was added at a rate such that temperature did not exceed 12". Then 16.8 g.(0.1 mole) of finely-ground 1, 3-6, 8-diendomethylene-l, 3, 6, 8- tetrazacyclodecane was added at a rate such that a temperature of 5-10'was maintained (17 rnin.). After 10 hr. subsequently at 0" the system was poured into 600 g. of ice and 100 ml. ...