Abstract Seven daunorubicin analogs containing α-l-, α-d-, and β-d-glycosidic linkages, in which the natural occurring sugar (l-daunosamine) was replaced by diastereo-isomeric 3- amino-2, 3, 6-trideoxyhexoses (3-epi-l-daunosamine, d-acosamine, d-daunosamine, d- ristosamine, and 3-epi-d-daunosamine), were prepared. In all cases, glycosidation with daunomycinone was performed in the presence of p-toluene-sulfonic acid starting from 1- ...
![a-D-arabino-Hexopyranoside, methyl2,3,6-trideoxy-3-[(trifluoroacetyl)amino]- (9CI) Structure](https://image.chemsrc.com/caspic/127/64519-41-1.png)
