Carbohydrate Research

Hémisynthèse de nouveaux glycosides analogues de la daunorubicine

J Boivin, A Montagnac, C Monneret, M Paīs

文献索引：Boivin, Jean; Montagnac, Alain; Monneret, Claude; Pais, Mary Carbohydrate Research, 1980 , vol. 85, p. 223 - 242

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被引用次数: 18

摘要

Abstract Seven daunorubicin analogs containing α-l-, α-d-, and β-d-glycosidic linkages, in which the natural occurring sugar (l-daunosamine) was replaced by diastereo-isomeric 3- amino-2, 3, 6-trideoxyhexoses (3-epi-l-daunosamine, d-acosamine, d-daunosamine, d- ristosamine, and 3-epi-d-daunosamine), were prepared. In all cases, glycosidation with daunomycinone was performed in the presence of p-toluene-sulfonic acid starting from 1- ...