… Pd-N Bond Rupture. X-ray Molecular Structure of [{Pd (η3-C4H7)} 2 (Me-BPzTO)](4-MeC6H4SO3)[Me-BPzTO= 4, 6-Bis (4-methylpyrazol-1-yl)-1, 3, 5-triazin-2-olate]

F Gomez-de la Torre, A de la Hoz, FA Jalon…

Index: Elguero, Jose; Fruchier, Alain; De La Hoz, Antonio; Jalon, Felix A.; Manzao, Blanca R.; Oteroo, Antonio; Torre, Felipe Gomez-De La Chemische Berichte, 1996 , vol. 129, # 5 p. 589 - 594

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Citation Number: 28

Abstract

Several bis-or tris (pyrazol-1-yl) triazine derivatives have been synthesized and used as ligands in the synthesis of cationic allyl-or bis (pentafluorophenyl) palladium complexes. In bis-palladated complexes hydrolysis of one pyrazole group is seen. The allyl palladium complexes show fluxional behavior, implying apparent π-allyl rotation and metallotropic shifts. Different activation energies, related to the strength of the Pd-N bond to be broken, ...