Tetrahedron

Efficient N-arylation catalyzed by a copper (I) pyrazolyl-nicotinic acid system

HY Liu, ZT Yu, YJ Yuan, T Yu, ZG Zou

Index: Liu, Hai-Yang; Yu, Zhen-Tao; Yuan, Yong-Jun; Yu, Tao; Zou, Zhi-Gang Tetrahedron, 2010 , vol. 66, # 47 p. 9141 - 9144

Full Text: HTML

Citation Number: 11

Abstract

Catalyst 6-(1H-pyrazol-1-yl) nicotinic acid L-CuCl behaves as a very active promoter of the N- arylation reactions, as it has been demonstrated with varieties of substrates under mild reaction conditions. A Cu (I) complex based on L of precatalyst has been isolated by a hydrothermal method and structurally characterized.

 Related Synthetic Route
3,5-Dimethylpyrazole Structure

67-51-6

3,5-Dimethylpyrazole

Bromobenzene Structure

108-86-1

Bromobenzene

~80%

3,5-DIMETHYL-1-PHENYLPYRAZOLE Structure

1131-16-4

3,5-DIMETHYL-1-...

2-Bromopyridine Structure

109-04-6

2-Bromopyridine

3,5-Dimethylpyrazole Structure

67-51-6

3,5-Dimethylpyrazole

~96%

2-(3,5-dimethylpyrazol-1-yl)pyridine Structure

21018-71-3

2-(3,5-dimethyl...

Pyrazole Structure

288-13-1

Pyrazole

2-Bromopyridine Structure

109-04-6

2-Bromopyridine

~99%

pyridyl-pyrazole Structure

25700-11-2

pyridyl-pyrazole


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved