Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations

T Wdowik, C Samojłowicz, M Jawiczuk…

Index: Wdowik, Tomasz; Samojlowicz, Cezary; Jawiczuk, Magdalena; Malinska, Maura; Wozniak, Krzysztof; Grela, Karol Chemical Communications, 2013 , vol. 49, # 7 p. 674 - 676

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Citation Number: 13

Abstract

Novel ruthenium (II) complexes were obtained as a result of a stoichiometric reaction of Grubbs' benzylidene second generation catalysts with 3-nitropropene. These stable complexes, formally ruthenaisoxazole N-oxide derivatives, display activity in both metathesis and non-metathetic processes such as cycloisomerisation, isomerisation and transfer hydrogenation.

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