Journal of the American Chemical Society

Cyclopropanes. XX. 1 1-Benzoyl-6-nitrobicyclo [3, 1, 0] hexane: Behavior toward Alkaline Reagents

LI Smith, RM Scribner

Index: Smith; Scribner Journal of the American Chemical Society, 1956 , vol. 78, p. 3412,3415

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Citation Number: 6

Abstract

In order to examine further the hypothesis that acetylenic or allenic ketones are intermediates in the reaction between secondary nitrocyclopropyl ketones and bases, or sodiomalonic esters, whereby 1, 3-diketones (or their derivatives) or a-pyrone esters are produced, respectively, the bicyclic secondary nitrocyclopropyl ketone I, named in the title, has been prepared and subjected to the action of these reagents. In this case the ...