Solvent extraction of metal ions from nitric acid solution using N, N′-substituted malonamides. Experimental and crystallographic evidence for two mechanisms of …

…, JO Liljenzin, M Skålberg, L Spjuth, C Madic

Index: Chan, Gabriel Y. S.; Drew, Michael G. B.; Hudson, Michael J.; Iveson, Peter B.; Liljenzin, Jan-Olov; Skalberg, Mats; Spjuth, Lena; Madic, Charles Journal of the Chemical Society - Dalton Transactions, 1997 , # 4 p. 649 - 660

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Citation Number: 86

Abstract

The solvent extraction of actinides including Am III and Cm III together with some trivalent lanthanides from nitric acid solutions by two newly synthesized malonamides, N, N′- dimethyl-N, N′-diphenyltetradecylmalonamide (dmptdma) and N, N′-dicyclohexyl-N, N′- dimethyltetradecylmalonamide (dcmtdma) has been investigated and compared with data for the reference malonamide, N, N′-dibutyl-N, N′-dimethyloctadecylmalonamide ( ...