Triorganotin (IV) benzoates and aminobenzoates

GK Sandhu, SP Verma, LS Moore, RV Parish

Index: Sandhu, G. K.; Verma, S. P.; Moore, L. S.; Parish, R. V. Journal of Organometallic Chemistry, 1987 , vol. 321, p. 15 - 26

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Citation Number: 17

Abstract

Abstract Complexes of the general formula R 3 SnX, where X is the anion of benzoic acid, o- , m-, p-amino-or N-phenyl-o-amino-benzoic acid, have been prepared and characterised. A combination of molecular weight, infrared, 1 H NMR and 119 Sn Mössbauer measurements show that, the amino-nitrogen atoms are not coordinated to tin. When R= phenyl or cyclohexyl, the compounds are monomeric and four-coordinate, and when R is alkyl (Me, ...