Journal of the American Chemical Society

Bimetallic catalysis. A new method for the activation of chloroarenes toward palladium-catalyzed coupling with olefins

JJ Bozell, CE Vogt

Index: Bozell, Joseph J.; Voght, Charles E. Journal of the American Chemical Society, 1988 , vol. 110, # 8 p. 2655 - 2657

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Citation Number: 77

Abstract

13 85 50 0 dba= dibenzylideneacetone. chromatographic purification gives the desired product. The reaction is best performed in two stages; combining the components simultaneously results in a lower yield. Appropriate control reactions verify the necessity of having both nickel and palladium catalysts present in the mixture. The results for a number of chloroarenes are given in Table I. The reaction is tolerant of both electron-donating and ...