Tetrahedron

Palladium-catalyzed carbene insertion into benzyl bromides

KL Greenman, DL Van Vranken

Index: Greenman, Kevin L.; Van Vranken, David L. Tetrahedron, 2005 , vol. 61, # 26 p. 6438 - 6441

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Citation Number: 66

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Palladium can catalyze the insertion of ethyl diazoacetate into benzyl bromides. The key step in the catalytic cycle is the migratory insertion of a carbene, derived from ethyl diazoacetate, into a Pd–C bond. ... Precedented insertion of TMSD. Precedented insertion of TMSD.