Tetrahedron

Synthesis, characterization, and applications in Heck and Suzuki coupling reactions of amphiphilic cyclopalladated ferrocenylimines

B Mu, T Li, W Xu, G Zeng, P Liu, Y Wu

Index: Mu, Bing; Li, Tiesheng; Xu, Wenjian; Zeng, Guoliang; Liu, Pingping; Wu, Yangjie Tetrahedron, 2007 , vol. 63, # 46 p. 11475 - 11488

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Citation Number: 55

Abstract

A series of novel amphiphilic ferrocenylimines and their cyclopalladated complexes of general formula [Fe (η5-C5H5)(η5-C5H4CR1NR2)](R1= H, R2= C12H25-n4a, R1= H, R2= C16H33-n4b, R1= CH3, R2= C12H25-n4c, R1= CH3, R2= C16H33-n4d),[PdCl {[(η5-C5H5)] Fe [(η5-C5H3) CR1NR2]}] 2 (5a–d),[PdCl {[(η5-C5H5)] Fe [(η5-C5H3)–CR1NR2]}(PPh3)](6a– d), were prepared and characterized by 1H NMR, 13C NMR, 31P NMR, IR, HRMS, and ...