Transformations of p-menthadienes under the action of potassium tert-butanolate in dimethyl sulfoxide

EF Buinova, TR Urbanovich, BG Udarov…

Index: Buinova, E. F.; Urbanovich, T. R.; Udarov, B. G.; Izotova, L. V. Chemistry of Natural Compounds, 1982 , vol. 18, p. 555 - 559 Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 5 p. 587 - 591

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Abstract

Abstract The products of the transformation of α-and γ-terpinenes, terpinolene,(+)- transisolimonene, and (+)-limonene under the action of potassium tert-butanolate in dimethyl sulfoxide contained—in addition to the α-and γ-terpinenes, isoterpinolene, p- mentha-3, 8-diene and p-cymene found previously—terpinolene, α-and β-phellandrenes, p- mentha-2, 4-diene (in a total amount of 1–3%), and polymers. Under these conditions, ...