Eu (fod) 3-catalyzed rearrangement of allylic methoxyacetates

BK Shull, T Sakai, M Koreeda

Index: Shull, Brian K.; Sakai, Takashi; Koreeda, Masato Journal of the American Chemical Society, 1996 , vol. 118, # 46 p. 11690 - 11691

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Citation Number: 23

Abstract

Stereo-and regiocontrolled allylic rearrangement reactions have played a central role in synthetic organic chemistry. 1 A number of the stereoselective rearrangement reactions of allylic esters to their more stable regioisomers have been reported in the literature2 including those that utilize various transition metals as catalysts. 3 However, these reactions are usually carried out under harsh conditions and are often plagued with low selectivity ...