Journal of the American Chemical Society

Steroids. XVI. Beckmann Rearrangement of 17-Ketosteroid Oximes1

ST Kaufmann

Index: Kaufmann Journal of the American Chemical Society, 1951 , vol. 73, p. 1779

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Citation Number: 24

Abstract

The identification of the dehydroto the Beckmann rearrangement. benzoate) with a six- membered D-ring can be considered as nitrogen analogs of the D-homosteroids. NH-group has been established by selenium dehydrogenation of one of these lactams. genation product as 1-azachrysene proves that the NH-group is in the 17a-position.