Tetrahedron letters

Effective dephosphorylation catalyzed by fluoride ion: A novel synthesis of terminal f-alkylacetylenes from f-alkanoyl chlorides

T Ishihara, T Maekawa, T Ando

Index: Ishihara, Takashi; Maekawa, Takashige; Ando, Teiichi Tetrahedron Letters, 1984 , vol. 25, # 13 p. 1377 - 1378

Full Text: HTML

Citation Number: 28

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... 1H-F-Alkene-1-phosphonates, easily accessible from F-alkanoyl chlorides, underwent dephosphorylation on treatment with a catalytic amount of fluoride ion at O°C to room temperature to give terminal F-alkylacetylenes in good yields. ... The spectroscopic properties (IR, NMR, and mass ...

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