The Journal of organic chemistry

Combined Directed Remote Metalation− Transition Metal Catalyzed Cross Coupling Strategies: The Total Synthesis of the Aglycones of the Gilvocarcins V, M, and E …

CA James, V Snieckus

Index: James, Clint A.; Snieckus, Victor Journal of Organic Chemistry, 2009 , vol. 74, # 11 p. 4080 - 4093

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Citation Number: 69

Abstract

A key directed remote metalation (DreM)− carbamoyl migration strategy was applied in an efficient synthesis of the naturally occurring 6H-naphtho [1, 2-b] benzopyran-6-one defucogilvocarcin V (1a, Scheme 11). The required biarylcarbamate 33d was best prepared by a high yielding Suzuki coupling reaction of 31a with the differentially protected trioxygenated naphthalene coupling partner 32d which was synthesized using a selective ...

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Selective dealkylations of aryl alkyl ethers and thioethers ...

[Testaferri, L.; Tiecco, M.; Tingoli, M.; Chianelli, D.; Montanucci, M. Tetrahedron, 1982 , vol. 38, # 24 p. 3687 - 3692]

Practical synthesis of aromatic ethers by SN Ar of fluoroben...

[Rodriguez, Juan R.; Agejas, Javier; Bueno, Ana B. Tetrahedron Letters, 2006 , vol. 47, # 32 p. 5661 - 5663]

Photodehalogenation of the monochloro-and monofluoroanisoles

[Siegman, John R.; Houser, John J. Journal of Organic Chemistry, 1982 , vol. 47, # 14 p. 2773 - 2779]