Chemical communications

A new mechanism for nucleophilic substitution at a thiophosphoryl centre revealed by the reaction of diisopropylamine with PSCl 3

MJP Harger

Index: Harger, Martin J. P. Chemical Communications, 2005 , # 22 p. 2863 - 2865

Full Text: HTML

Citation Number: 3

Abstract

The diisopropylamino phosphorothioic dichloride 1 (R = Pr i ) is a known compound but the ways in which it has been obtained are not straightforward. 3 We hoped it could be simply prepared by the direct reaction of PSCl 3 with Pr i 2 NH but that proved not to be the case.† Since S N