Chemical communications

A new mechanism for nucleophilic substitution at a thiophosphoryl centre revealed by the reaction of diisopropylamine with PSCl 3

MJP Harger

文献索引：Harger, Martin J. P. Chemical Communications, 2005 , # 22 p. 2863 - 2865

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被引用次数: 3

摘要

The diisopropylamino phosphorothioic dichloride 1 (R = Pr i ) is a known compound but the ways in which it has been obtained are not straightforward. 3 We hoped it could be simply prepared by the direct reaction of PSCl 3 with Pr i 2 NH but that proved not to be the case.† Since S N