Journal of organometallic chemistry

Carbene adduct of cyclopalladated ferrocenylimine as an efficient catalyst for the amination of aryl chlorides

J Li, M Cui, A Yu, Y Wu

Index: Li, Jingya; Cui, Mengjun; Yu, Ajuan; Wu, Yangjie Journal of Organometallic Chemistry, 2007 , vol. 692, # 17 p. 3732 - 3742

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Citation Number: 6

Abstract

A novel air-and moisture-stable carbene adduct of cyclopalladated ferrocenylimine has been synthesized and characterized. The structure of this compound was determined by X- ray crystal structure analysis. This adduct has been applied as an efficient catalyst for the amination of aryl chlorides.

 Related Synthetic Route
Chlorobenzene Structure

108-90-7

Chlorobenzene

2,6-xylidine Structure

87-62-7

2,6-xylidine

~94%

2,6-dimethyl-N-phenylaniline Structure

4058-04-2

2,6-dimethyl-N-...

2-Chloroanisole Structure

766-51-8

2-Chloroanisole

2,6-xylidine Structure

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2,6-xylidine

~97%

N-(2-Methoxyphenyl)-2,6-dimethylaniline Structure

58656-24-9

N-(2-Methoxyphe...

2-Amino-p-xylene Structure

95-78-3

2-Amino-p-xylene

Chlorobenzene Structure

108-90-7

Chlorobenzene

~96%

2,5-Dimethyl-N-phenylaniline Structure

32446-14-3

2,5-Dimethyl-N-...

Dodecanamine Structure

124-22-1

Dodecanamine

Chlorobenzene Structure

108-90-7

Chlorobenzene

~41%

N-Dodecylaniline Structure

3007-74-7

N-Dodecylaniline

N-dodecyl-N-phenylaniline Structure

78204-99-6

N-dodecyl-N-phe...

4-Chlorotoluene Structure

106-43-4

4-Chlorotoluene

Cyclohexylamine Structure

108-91-8

Cyclohexylamine

~90%

N-cyclohexyl-4-methylaniline Structure

10386-93-3

N-cyclohexyl-4-...

morpholine Structure

110-91-8

morpholine

2-Chlorotoluene Structure

95-49-8

2-Chlorotoluene

~10%

4-O-TOLYLMORPHOLINE Structure

7178-40-7

4-O-TOLYLMORPHOLINE

4-Chlorotoluene Structure

106-43-4

4-Chlorotoluene

2-Amino-p-xylene Structure

95-78-3

2-Amino-p-xylene

~95%

2,5-DIMETHYL-N-P-TOLYLANILINE Structure

34160-15-1

2,5-DIMETHYL-N-...


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