Chirality

Enantiomerization and Enantioselective Bioaccumulation of Metalaxyl

Y Gao, H Wang, F Qin, P Xu, X Lv, J Li, B Guo

Index: Gao, Yongxin; Wang, Huili; Qin, Fang; Xu, Peng; Lv, Xiaotian; Li, Jianzhong; Guo, Baoyuan Chirality, 2014 , vol. 26, # 2 p. 88 - 94

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Citation Number: 4

Abstract

ABSTRACT The enantiomerization and enantioselective bioaccumulation of metalaxyl by a single dose of exposure to Tenebrio molitor larvae under laboratory condition were studied by high-performance liquid chromatography tandem mass spectroscopy (HPLC-MS/MS) based on a ChiralcelOD-3R [cellulosetris-tris-(3, 5-dichlorophenyl-carbamate)] column. Exposure of enantiopure R-metalaxyl and S-metalaxyl in Tenebrio molitor larvae exhibited ...