Organic Process Research & Development

Palladium on Charcoal as a Catalyst for Stoichiometric Chemo-and Stereoselective Hydrosilylations and Hydrogenations with Triethylsilane

S Tuokko, PM Pihko

Index: Kumpulainen, Esa T. T.; Koskinen, Ari M. P.; Rissanen, Kari Organic Letters, 2007 , vol. 9, # 24 p. 5043 - 5045

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Citation Number: 5

Abstract

... Volume: Page ... Alternatively, with a 3-fold excess of Et 3 SiH, chemoselective reductions of S-ethylthioesters with Pd/C (Fukuyama reduction) constitute a well-established protocol in synthetic organic chemistry.(14 ... 5, Pd/C (5 wt %) (vacuum treated) f, 2 mg, 91%, 9%. ...