Tetrahedron letters

Acyloin rearrangement of α-hydroxy acetals: Application to the methyl l-mycaroside synthesis

T Sato, T Nagata, K Maeda, S Ohtsuka

Index: Sato, Tadashi; Nagata, Tsutomu; Maeda, Kenji; Ohtsuka, Sawako Tetrahedron Letters, 1994 , vol. 35, # 28 p. 5027 - 5030

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Citation Number: 6

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Acid treatment of α-hydroxy acetals induced 1,2-alkyl, aryl, or alkenyl migration. An alkenyl migration product was utilized as a starting material of methyl l-mycaroside synthesis. ... Acid-treatment of α-hydroxy acetals 1 induced 1,2-migration to afford α-alkoxy-β,γ-enones 2. One of the ...