Organic Synthesis Using Organosulfur-Nitrites and-Nitrates

YH Kim

Index: Kim, Yong Hae Phosphorus, Sulfur and Silicon and the Related Elements, 1993 , vol. 74, # 1-4 p. 249 - 260

Full Text: HTML

Citation Number: 9

Abstract

Abstract Thionitrites or thionitrates have been considered to be unstable However, bulky groups' thio-NOn such as t-butylthio-nitrites and-nitrates have been readily synthesized and found to be stable enough for the use of the useful organic syntheses as an excellent nitrosation and diazotization reagents under mild conditions. Direct conversion of amines to the corresponding halides in the presence of copper halides (II), fluorination of ...