Modified Ullmann coupling of 2-chloro-3-trifluoromethylpyridine

…, LL Szafraniec, WT Beaudry, DK Rohrbaugh…

Index: Munavalli, S.; Rossman, D. I.; Szafraniec, L. L.; Beaudry, W. T.; Rohrbaugh, D. K.; et al. Journal of Fluorine Chemistry, 1995 , vol. 73, # 1 p. 1 - 6

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Citation Number: 8

Abstract

The application of the modified Ullmann reaction to 2-chloro-3-trifluoromethylpyridine furnishes 5, 5′-bis (trifluoromethyl)-2, 2′-bipyridine as the primary product, accompanied by small amounts of the expected 3, 3′-bis (trifluoromethyl)-2, 2′-bipyridine, 2-benzyl-3- (trifluoromethyl) pyridine, bibenzyl, 3-trifluoromethylpyridine, 3-methylpyridine, 2- hydroxyethyl-(3-trifluoromethylpyridyl) ether and 2-hydroxyethyl-(3-methylpyridyl) ether. ...