The Journal of Organic Chemistry

Oxidation of nitronates with persulfate and with silver ions

AH Pagano, H Shechter

Index: Pagano,A.H.; Shechter,H. Journal of Organic Chemistry, 1970 , vol. 35, p. 295 - 303

Full Text: HTML

Citation Number: 49

Abstract

Sodium or ammonium persulfates convert salts of primary nitro compounds into secondary vicinal dinitro compounds (RCHNGzCHNOzR) and aldehydes. Silver ion catalyzes the oxidation-reduction reactions, and advantageous specific procedures using buffers and heterogeneous extractants are described for effecting oxidative dimerization, Experimental methods have been developed which minimize transformation of the oxidative dimers to ...

Interesting products derived from the reactions of 2, 3-diam...

[Gagnon, Janet L.; Walters, Thomas R.; Zajac, Walter W.; Buzby, John H. Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6712 - 6715]

Sur la reactivite de gem-bromonitroalcanes en presence de th...

[Amrollah-Madjdabadi, Ali; Beugelmans, Rene; Lechevallier, Andre Tetrahedron Letters, 1987 , vol. 28, # 39 p. 4525 - 4528]

Ion pairing and solvent effects in the reactivity of anions ...

[Russell, Glen A.; Ros, Francisco; Mudryk, Boguslaw Journal of the American Chemical Society, 1980 , vol. 102, # 25 p. 7601 - 7603]

The mechanism of catalyst deactivation and by-product format...

[Wang, Yi; Zhang, Shengjian; Zhao, Yingxian; Lin, Min Journal of Molecular Catalysis A: Chemical, 2014 , vol. 385, p. 1 - 6]

Nucleic Acid Related Compounds. 105. Synthesis of 2', 3'-Did...

[Park, Kwanghee Koh; Lee, Chul Woo; Choi, Sook Young Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 5 p. 601 - 604]