Poly (ethylene glycol) as a Reaction Matrix in Platinum??or Gold??Catalyzed Cycloisomerization: A Mechanistic Investigation

…, E Colacino, J Martinez, F Lamaty

Index: Spina, Rosella; Colacino, Evelina; Martinez, Jean; Lamaty, Frederic Chemistry - A European Journal, 2013 , vol. 19, # 12 p. 3817 - 3821

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Citation Number: 9

Abstract

Transition-metal-catalyzed cycloisomerization has recently become a fundamental chemical transformation for the synthesis of a large variety of organic molecules including heterocycles.[1] Usually, the reaction is performed under homogeneous conditions: a starting material is stirred in an organic solvent with a metallic salt, often under conventional heating in an oil bath. Treatment of the reaction including aqueous work-up, followed by ...