Mechanistic aspects of the reaction of anionic iron (0)-olefin complexes with organic halides. Detection and characterization of paramagnetic organometallic …

DH Hill, MA Parvez, A Sen

Index: Hill, Dale H.; Parvez, Masood A.; Sen, Ayusman Journal of the American Chemical Society, 1994 , vol. 116, # 7 p. 2889 - 2901

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Citation Number: 50

Abstract

Abstract: The scope and the mechanism of the reactions of [CpFe (COD)][Li (TMEDA)(Cp= C~ HS-; COD= 1, 5-cyclooctadiene; TMEDA= Me2NCH2CH2NMe2), 1, with a number of organic monohalides and geminal dihalides were investigated. With monohalides organic coupling products were observed, and, in particular, the coupling and cross-coupling of benzyl and allyl halides were studied in detail. The addition of 1 equiv of benzyl halide to ...

~23%

~12%

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