Stereodynamics of 2-(Diethylamino) propane and 2-(Dibenzylamino) propane. 1H and 13C {1H} DNMR Studies. Molecular Mechanics Calculations

JH Brown, CH Bushweller

Index: Brown, Jay H.; Bushweller, C. Hackett Journal of the American Chemical Society, 1995 , vol. 117, # 50 p. 12567 - 12577

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Citation Number: 10

Abstract

Abstract: 2-(Diethy1amino) propane (DEAP) and 2-(dibenzy1amino) propane (DBAP) possess similar molecular symmetries. Interconversion among the stable equilibrium conformations occurs by inversion-rotation at the pyramidal nitrogen and by isolated rotation about carbon-nitrogen bonds. In DEAP and DBAP, the fact that stable equilibrium conformations cannot have destabilizing syn-l, 5 interactions between methyl or phenyl ...