Silicadiphenyl phosphinite (SDPP)/Pd (0) nanocatalyst for efficient aminocarbonylation of aryl halides with POCl 3 and DMF

N Iranpoor, H Firouzabadi, S Motevalli

Index: Iranpoor, Nasser; Firouzabadi, Habib; Motevalli, Somayeh Journal of Molecular Catalysis A: Chemical, 2012 , vol. 355, p. 69 - 74

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Citation Number: 17

Abstract

Silicadiphenyl phosphinite (SDPP) as a new phosphorylated silica and catalytic amounts of Pd (II) generates nano SDPP/Pd (0) catalyst for the efficient aminocarbonylation of aryl halides in the presence of POCl3 and N, N-dimethylformamide (DMF). Amides are obtained in high yields from aryl iodides and also activated aryl bromides, chlorides.