Diels-Alder reactions of 1-azadienes

YS Cheng, AT Lupo Jr, FW Fowler

Index: Cheng,Y.S.; Lupo,A.T.; Fowler,F.W. Journal of the American Chemical Society, 1983 , vol. 105, p. 7696

Full Text: HTML

Citation Number: 77

Abstract

Abstract: N-Acyl-1-azadienes have been prepared by the thermal elimination of acetic acid from 0-acetylhydroxylamine derivatives. These reactive compounds have been observed to undergo the intramolecular Diels-Alder reaction to give piperidine derivatives. Studies on substituted azadienes suggest that the reaction follows predominantly an exo stereochemical pathway.

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[(2-cyclopent-2-en-1-ylacetyl)-prop-2-enylamino] acetate Structure

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[pent-4-enoyl(pent-3-en-2-yl)amino] acetate Structure

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(E)-4-bromopent-2-ene Structure

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[cyclohexen-1-ylmethyl(pent-4-enoyl)amino] acetate Structure

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1-(bromomethyl)cyclohex-1-ene Structure

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[cyclohexen-1-ylmethyl(pent-4-enoyl)amino] acetate Structure

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[acetyl(cyclohexen-1-ylmethyl)amino] acetate Structure

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4-Pentenoyl chloride Structure

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(but-2-enylamin...

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[but-2-enyl(pent-4-enoyl)amino] acetate Structure

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[acetyl(but-2-enyl)amino] acetate Structure

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[hex-5-enoyl(prop-2-enyl)amino] acetate Structure

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1,2,3,8,9,9a-hexahydroquinolizin-4-one Structure

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hex-5-enoyl chloride Structure

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1,2,3,8,9,9a-hexahydroquinolizin-4-one Structure

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[pent-4-enoyl(prop-2-enyl)amino] acetate Structure

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4-Pentenoyl chloride Structure

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2,7,8,8a-tetrahydro-1H-indolizin-3-one Structure

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[pent-4-ynoyl(prop-2-enyl)amino] acetate Structure

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[acetyl(prop-2-enyl)amino] acetate Structure

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[pent-4-ynoyl(prop-2-enyl)amino] acetate Structure

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[pent-4-ynoyl(p...

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[acetyl(prop-2-enyl)amino] acetate Structure

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[acetyl(prop-2-...

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(prop-2-enylamino) acetate Structure

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(prop-2-enylami...

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[acetyl(cyclohexen-1-ylmethyl)amino] acetate Structure

87842-89-5

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(cyclohexen-1-ylmethylamino) acetate Structure

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1-(bromomethyl)cyclohex-1-ene Structure

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(cyclohexen-1-ylmethylamino) acetate Structure

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hex-5-enoyl chloride Structure

36394-07-7

hex-5-enoyl chloride

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[hex-5-enoyl(prop-2-enyl)amino] acetate Structure

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[hex-5-enoyl(pr...

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[acetyl(prop-2-enyl)amino] acetate Structure

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[acetyl(prop-2-...

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[hex-5-enoyl(prop-2-enyl)amino] acetate Structure

77413-80-0

[hex-5-enoyl(pr...

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(E)-4-bromopent-2-ene Structure

56535-63-8

(E)-4-bromopent...

acetamido acetate Structure

7340-09-2

acetamido acetate

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[acetyl(pent-3-en-2-yl)amino] acetate Structure

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