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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Diels-Alder reactions of 1-azadienes

YS Cheng, AT Lupo Jr, FW Fowler

文献索引：Cheng,Y.S.; Lupo,A.T.; Fowler,F.W. Journal of the American Chemical Society, 1983 , vol. 105, p. 7696

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被引用次数: 77

摘要

Abstract: N-Acyl-1-azadienes have been prepared by the thermal elimination of acetic acid from 0-acetylhydroxylamine derivatives. These reactive compounds have been observed to undergo the intramolecular Diels-Alder reaction to give piperidine derivatives. Studies on substituted azadienes suggest that the reaction follows predominantly an exo stereochemical pathway.

2-(cyclopent-2-enyl)acetic acid chloride结构式

2-(cyclopent-2-...

(prop-2-enylamino) acetate结构式

(prop-2-enylami...

~66%

[(2-cyclopent-2-en-1-ylacetyl)-prop-2-enylamino] acetate结构式

[(2-cyclopent-2...

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[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~%

[(2-cyclopent-2-en-1-ylacetyl)-prop-2-enylamino] acetate结构式

[(2-cyclopent-2...

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[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~67%

N-(1-methoxyprop-2-enyl)acetamide结构式

N-(1-methoxypro...

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acetamido acetate结构式

acetamido acetate

1-溴甲基环已烯结构式

1-溴甲基环已烯

~66%

[acetyl(cyclohexen-1-ylmethyl)amino] acetate结构式

[acetyl(cyclohe...

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[pent-4-enoyl(prop-2-enyl)amino] acetate结构式

[pent-4-enoyl(p...

~%

N-prop-2-enylpent-4-enamide结构式

N-prop-2-enylpe...

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4-戊烯酰氯结构式

~%

N-prop-2-enylpent-4-enamide结构式

N-prop-2-enylpe...

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N-(1-methoxyprop-2-enyl)acetamide结构式

N-(1-methoxypro...

~%

Acetamide,N-2-propen-1-yl结构式

Acetamide,N-2-p...

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[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~%

Acetamide,N-2-propen-1-yl结构式

Acetamide,N-2-p...

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4-戊烯酰氯结构式

(pent-3-en-2-ylamino) acetate结构式

(pent-3-en-2-yl...

~31%

[pent-4-enoyl(pent-3-en-2-yl)amino] acetate结构式

[pent-4-enoyl(p...

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(E)-4-bromopent-2-ene结构式

(E)-4-bromopent...

~%

[pent-4-enoyl(pent-3-en-2-yl)amino] acetate结构式

[pent-4-enoyl(p...

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[acetyl(pent-3-en-2-yl)amino] acetate结构式

[acetyl(pent-3-...

~%

[pent-4-enoyl(pent-3-en-2-yl)amino] acetate结构式

[pent-4-enoyl(p...

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4-戊烯酰氯结构式

(cyclohexen-1-ylmethylamino) acetate结构式

(cyclohexen-1-y...

~74%

[cyclohexen-1-ylmethyl(pent-4-enoyl)amino] acetate结构式

[cyclohexen-1-y...

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1-溴甲基环已烯结构式

1-溴甲基环已烯

~%

[cyclohexen-1-ylmethyl(pent-4-enoyl)amino] acetate结构式

[cyclohexen-1-y...

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[acetyl(cyclohexen-1-ylmethyl)amino] acetate结构式

[acetyl(cyclohe...

~%

[cyclohexen-1-ylmethyl(pent-4-enoyl)amino] acetate结构式

[cyclohexen-1-y...

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4-戊烯酰氯结构式

(but-2-enylamino) acetate结构式

(but-2-enylamin...

~86%

[but-2-enyl(pent-4-enoyl)amino] acetate结构式

[but-2-enyl(pen...

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[acetyl(but-2-enyl)amino] acetate结构式

[acetyl(but-2-e...

~%

[but-2-enyl(pent-4-enoyl)amino] acetate结构式

[but-2-enyl(pen...

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[hex-5-enoyl(prop-2-enyl)amino] acetate结构式

[hex-5-enoyl(pr...

~69%

1,2,3,8,9,9a-hexahydroquinolizin-4-one结构式

1,2,3,8,9,9a-he...

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5-己酰氯结构式

~%

1,2,3,8,9,9a-hexahydroquinolizin-4-one结构式

1,2,3,8,9,9a-he...

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[pent-4-enoyl(prop-2-enyl)amino] acetate结构式

[pent-4-enoyl(p...

~77%

2,7,8,8a-tetrahydro-1H-indolizin-3-one结构式

2,7,8,8a-tetrah...

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methyl [pent-4-enoyl(prop-2-enyl)amino] carbonate结构式

methyl [pent-4-...

~65%

2,7,8,8a-tetrahydro-1H-indolizin-3-one结构式

2,7,8,8a-tetrah...

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4-戊烯酰氯结构式

~%

2,7,8,8a-tetrahydro-1H-indolizin-3-one结构式

2,7,8,8a-tetrah...

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N-hydroxy-N-prop-2-enylpent-4-enamide结构式

N-hydroxy-N-pro...

~%

2,7,8,8a-tetrahydro-1H-indolizin-3-one结构式

2,7,8,8a-tetrah...

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N-prop-2-enylhydroxylamine结构式

N-prop-2-enylhy...

4-戊烯酰氯结构式

~53%

N-hydroxy-N-prop-2-enylpent-4-enamide结构式

N-hydroxy-N-pro...

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1-溴-2-丁烯结构式

acetamido acetate结构式

acetamido acetate

~57%

[acetyl(but-2-enyl)amino] acetate结构式

[acetyl(but-2-e...

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[acetyl(but-2-enyl)amino] acetate结构式

[acetyl(but-2-e...

~46%

(but-2-enylamino) acetate结构式

(but-2-enylamin...

查看详情

4-戊烯酰氯结构式

(prop-2-enylamino) acetate结构式

(prop-2-enylami...

~88%

[pent-4-enoyl(prop-2-enyl)amino] acetate结构式

[pent-4-enoyl(p...

查看详情

[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~%

[pent-4-enoyl(prop-2-enyl)amino] acetate结构式

[pent-4-enoyl(p...

查看详情

(prop-2-enylamino) acetate结构式

(prop-2-enylami...

氯甲酸烯丙酯结构式

氯甲酸烯丙酯

~49%

[prop-2-enoxycarbonyl(prop-2-enyl)amino] acetate结构式

[prop-2-enoxyca...

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[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~%

[prop-2-enoxycarbonyl(prop-2-enyl)amino] acetate结构式

[prop-2-enoxyca...

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(E)-4-bromopent-2-ene结构式

(E)-4-bromopent...

~%

(pent-3-en-2-ylamino) acetate结构式

(pent-3-en-2-yl...

查看详情

[acetyl(pent-3-en-2-yl)amino] acetate结构式

[acetyl(pent-3-...

~26%

(pent-3-en-2-ylamino) acetate结构式

(pent-3-en-2-yl...

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pent-4-ynoyl chloride结构式

pent-4-ynoyl ch...

(prop-2-enylamino) acetate结构式

(prop-2-enylami...

~51%

[pent-4-ynoyl(prop-2-enyl)amino] acetate结构式

[pent-4-ynoyl(p...

查看详情

[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~%

[pent-4-ynoyl(prop-2-enyl)amino] acetate结构式

[pent-4-ynoyl(p...

查看详情

[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~54%

(prop-2-enylamino) acetate结构式

(prop-2-enylami...

查看详情

[acetyl(cyclohexen-1-ylmethyl)amino] acetate结构式

[acetyl(cyclohe...

~38%

(cyclohexen-1-ylmethylamino) acetate结构式

(cyclohexen-1-y...

查看详情

1-溴甲基环已烯结构式

1-溴甲基环已烯

~%

(cyclohexen-1-ylmethylamino) acetate结构式

(cyclohexen-1-y...

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5-己酰氯结构式

(prop-2-enylamino) acetate结构式

(prop-2-enylami...

~86%

[hex-5-enoyl(prop-2-enyl)amino] acetate结构式

[hex-5-enoyl(pr...

查看详情

[acetyl(prop-2-enyl)amino] acetate结构式

[acetyl(prop-2-...

~%

[hex-5-enoyl(prop-2-enyl)amino] acetate结构式

[hex-5-enoyl(pr...

查看详情

(E)-4-bromopent-2-ene结构式

(E)-4-bromopent...

acetamido acetate结构式

acetamido acetate

~8%

[acetyl(pent-3-en-2-yl)amino] acetate结构式

[acetyl(pent-3-...

查看详情