Tetrahedron

Ethyl esters of malonanilic acids. Synthesis and pyrolysis

…, PA Bezugly, VI Treskach, SG Taran, OV Gorokhova

Index: Ukrainets, Igor V.; Bezugly, Peter A.; Treskach, Vladimir I.; Taran, Svetlana G.; Gorokhova, Olga V. Tetrahedron, 1994 , vol. 50, # 34 p. 10331 - 10338

Full Text: HTML

Citation Number: 21

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The pyrolysis under 170–220°C or boiling in DMF of malonanilic acids ethyl esters (2) is accompanied by formation of malonic acids symmetric dianilides (7) with high yields. A possible mechanism for this transformation has been suggested. ... Cookies are used by this site. To decline or ...

 Related Synthetic Route
2-carboxymalonanilic acid ethyl ester Structure

101646-18-8

2-carboxymalona...

~98%

2-[[3-(2-carboxyanilino)-3-oxopropanoyl]amino]benzoic acid Structure

77317-57-8

2-[[3-(2-carbox...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
Anthranilic acid Structure

118-92-3

Anthranilic acid

~%

2-[[3-(2-carboxyanilino)-3-oxopropanoyl]amino]benzoic acid Structure

77317-57-8

2-[[3-(2-carbox...

Learn More
4-ethoxymalonanilic acid ethyl ester Structure

4270-39-7

4-ethoxymalonan...

~97%

N,N'-bis(4-ethoxyphenyl)propanediamide Structure

4270-37-5

N,N'-bis(4-etho...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
2-Phenoxyethanamine Structure

156-43-4

2-Phenoxyethanamine

~%

N,N'-bis(4-ethoxyphenyl)propanediamide Structure

4270-37-5

N,N'-bis(4-etho...

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Propanoic acid, 3-[(2-methoxyphenyl)amino]-3-oxo-, ethyl ester Structure

90475-72-2

Propanoic acid,...

~93%

N1,N3-BIS(2-METHOXYPHENYL)MALONAMIDE Structure

7056-72-6

N1,N3-BIS(2-MET...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
2-Anisidine Structure

90-04-0

2-Anisidine

~%

N1,N3-BIS(2-METHOXYPHENYL)MALONAMIDE Structure

7056-72-6

N1,N3-BIS(2-MET...

Learn More
ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

~89%

N,N'-bis(2-hydroxyphenyl)propanediamide Structure

84755-34-0

N,N'-bis(2-hydr...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
aminophenol Structure

95-55-6

aminophenol

~%

N,N'-bis(2-hydroxyphenyl)propanediamide Structure

84755-34-0

N,N'-bis(2-hydr...

Learn More
ethyl 3-anilino-3-oxopropanoate Structure

53341-66-5

ethyl 3-anilino...

~85%

N,N'-Diphenylmalonamide Structure

621-10-3

N,N'-Diphenylma...

Diethyl malonate Structure

105-53-3

Diethyl malonate

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anhydride of malonic acid monoethyl ester Structure

140428-80-4

anhydride of ma...

o-Toluidine Structure

95-53-4

o-Toluidine

~86%

ethyl 3-(2-methylanilino)-3-oxopropanoate Structure

104330-53-2

ethyl 3-(2-meth...

Learn More
Monoethyl malonic acid Structure

1071-46-1

Monoethyl malon...

~%

ethyl 3-(2-methylanilino)-3-oxopropanoate Structure

104330-53-2

ethyl 3-(2-meth...

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ethyl 3-(2-methylanilino)-3-oxopropanoate Structure

104330-53-2

ethyl 3-(2-meth...

~92%

N,N''-DI-O-TOLYL-MALONAMIDE Structure

10378-79-7

N,N''-DI-O-TOLY...

Diethyl malonate Structure

105-53-3

Diethyl malonate

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Ethylmalonoyl dichloride Structure

36239-09-5

Ethylmalonoyl d...

2-Amino-5-bromobenzoic acid Structure

5794-88-7

2-Amino-5-bromo...

~94%

5-bromo-2-[(3-ethoxy-3-oxopropanoyl)amino]benzoic acid Structure

113117-47-8

5-bromo-2-[(3-e...

Learn More
ethyl 3-anilino-3-oxopropanoate Structure

53341-66-5

ethyl 3-anilino...

~0%

N,N'-Diphenylmalonamide Structure

621-10-3

N,N'-Diphenylma...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
ethyl 3-(2-methylanilino)-3-oxopropanoate Structure

104330-53-2

ethyl 3-(2-meth...

~0%

N,N''-DI-O-TOLYL-MALONAMIDE Structure

10378-79-7

N,N''-DI-O-TOLY...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
4-ethoxymalonanilic acid ethyl ester Structure

4270-39-7

4-ethoxymalonan...

~0%

N,N'-bis(4-ethoxyphenyl)propanediamide Structure

4270-37-5

N,N'-bis(4-etho...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
Propanoic acid, 3-[(2-methoxyphenyl)amino]-3-oxo-, ethyl ester Structure

90475-72-2

Propanoic acid,...

~0%

N1,N3-BIS(2-METHOXYPHENYL)MALONAMIDE Structure

7056-72-6

N1,N3-BIS(2-MET...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

~0%

N,N'-bis(2-hydroxyphenyl)propanediamide Structure

84755-34-0

N,N'-bis(2-hydr...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
4-[(3-ethoxy-1,3-dioxopropyl)amino]-benzoic acid Structure

130217-49-1

4-[(3-ethoxy-1,...

~0%

4-[[3-(4-carboxyanilino)-3-oxopropanoyl]amino]benzoic acid Structure

10256-16-3

4-[[3-(4-carbox...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
2-carboxymalonanilic acid ethyl ester Structure

101646-18-8

2-carboxymalona...

~0%

2-[[3-(2-carboxyanilino)-3-oxopropanoyl]amino]benzoic acid Structure

77317-57-8

2-[[3-(2-carbox...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
2-carboethoxymalonanilic acid ethyl ester Structure

146828-48-0

2-carboethoxyma...

~0%

N,N'-di-2-carboethoxyanilide of malonic acid Structure

100093-32-1

N,N'-di-2-carbo...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
2-carbomethoxymalonanilic acid ethyl ester Structure

159657-34-8

2-carbomethoxym...

~0%

N,N'-di-2-carbomethoxyanilide of malonic acid Structure

62640-76-0

N,N'-di-2-carbo...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
4-carboethoxymalonanilic acid ethyl ester Structure

159657-36-0

4-carboethoxyma...

~0%

N,N'-di-4-carboethoxyanilide of malonic acid Structure

19288-86-9

N,N'-di-4-carbo...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
4-[(3-ethoxy-1,3-dioxopropyl)amino]-benzoic acid Structure

130217-49-1

4-[(3-ethoxy-1,...

~95%

4-[[3-(4-carboxyanilino)-3-oxopropanoyl]amino]benzoic acid Structure

10256-16-3

4-[[3-(4-carbox...

Diethyl malonate Structure

105-53-3

Diethyl malonate

Learn More
4-Aminobenzoic acid Structure

150-13-0

4-Aminobenzoic acid

~%

4-[[3-(4-carboxyanilino)-3-oxopropanoyl]amino]benzoic acid Structure

10256-16-3

4-[[3-(4-carbox...

Learn More
aminophenol Structure

95-55-6

aminophenol

Diethyl malonate Structure

105-53-3

Diethyl malonate

~86%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
ethyl 3-anilino-3-oxopropanoate Structure

53341-66-5

ethyl 3-anilino...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
4-ethoxymalonanilic acid ethyl ester Structure

4270-39-7

4-ethoxymalonan...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
Propanoic acid, 3-[(2-methoxyphenyl)amino]-3-oxo-, ethyl ester Structure

90475-72-2

Propanoic acid,...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
4-[(3-ethoxy-1,3-dioxopropyl)amino]-benzoic acid Structure

130217-49-1

4-[(3-ethoxy-1,...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
2-carboxymalonanilic acid ethyl ester Structure

101646-18-8

2-carboxymalona...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
2-carboethoxymalonanilic acid ethyl ester Structure

146828-48-0

2-carboethoxyma...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
2-carbomethoxymalonanilic acid ethyl ester Structure

159657-34-8

2-carbomethoxym...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More
4-carboethoxymalonanilic acid ethyl ester Structure

159657-36-0

4-carboethoxyma...

~%

ethyl 3-(2-hydroxyanilino)-3-oxopropanoate Structure

55244-09-2

ethyl 3-(2-hydr...

Learn More

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