The Journal of organic chemistry

(Me3Si) 3SiH-Mediated Intermolecular Radical Perfluoroalkylation Reactions of Olefins in Water

S Barata-Vallejo, A Postigo

Index: Barata-Vallejo, Sebastian; Postigo, Al Journal of Organic Chemistry, 2010 , vol. 75, # 18 p. 6141 - 6148

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Citation Number: 34

Abstract

Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved through different methods, among which, the addition of perfluoroalkyl radicals to unsaturated bonds represents a convenient choice. On the other hand, intermolecular radical reactions in water have attracted the attention of synthetic chemists ...