Dehydrochlorination of hydroximic acid chlorides by the use of organotin compounds: an application for synthesis of isoxazolines and isoxazoles

O Moriya, Y Urata, T Endo

Index: Moriya, Osamu; Urata, Yoshikiyo; Endo, Takeshi Journal of the Chemical Society, Chemical Communications, 1991 , # 1 p. 17 - 18

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Citation Number: 13

Abstract

Nitrile oxides are known as the reactive intermediates for synthesis of a variety of heterocyclic compounds via [3 + 21 dipolar cycloaddition. 1 Several procedures for the preparation of these dipoles have been developed concurrently with the investigation into the synthetic application of the cycloaddi- tion reactions.2 The dehydrogenation of aldoximes, which seems to proceed through the formation of halogenated derivatives of aldoximes such as hydroximic acid ...