Tetrahedron letters

Novel desulfurization of thiocarbonyl compounds into their corresponding oxo-derivatives using a peroxy-sulfur intermediate generated from 2-nitrobenzenesulfonyl …

HK Yong, CC Bong, SC Hae

Index: Kim, Yong Hae; Chung, Bong Chul; Chang, Hae Sung Tetrahedron Letters, 1985 , vol. 26, # 8 p. 1079 - 1082

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Citation Number: 39

Abstract

Abstract Thiocarbonyl compounds such as substituted-thioureas,-thioamides and- thiocarbamates were found to react with a peroxysulfur intermediate (3) which is generated by the treatment of 2-nitrobenzenesulfonyl chloride with potassium superoxide to convert into the corresponding carbonyl compounds in quantitative yield at− 30 C in acetonitrile.

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