Heteroatom Chemistry

On the reaction of bis (phosphothioyl) disul??fanes with hydroxamic acids, part I: Ionic versus radical reaction pathways

W Przychodzeń, J Chojnacki

Index: Przychodzen, Witold; Chojnacki, Jaroslaw Heteroatom Chemistry, 2008 , vol. 19, # 3 p. 271 - 282

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Citation Number: 6

Abstract

Abstract Among sodium N-alkyl-4-chlorobenzo-hydroxamates treated with bis (phosphothioyl) disul-fanes> P (S) SSP (S)<(where> P (S) is phosphorothioyl, phosphonothioyl, and phosphinothioyl), only the N-methyl one yields quantitatively the respective O-phosphothioyl derivatives exhibiting complete inversion of configuration at phosphorus in a reaction whose products are inert toward dithiophosphate arising in the ...