Synthesis, structures and the biological activity study on the metal complexes of 2-(4-aminophenyl) benzothiazole derivative

…, JM Song, Y Lu, QJ Huang, K Song, J Zhou, T Lu

Index: Lin, Guo-Wu; Wang, Yue; Jin, Qiao-Mei; Yang, Tao-Tao; Song, Jie-Mei; Lu, Yi; Huang, Qing-Jie; Song, Ke; Zhou, Jun; Lu, Tao Inorganica Chimica Acta, 2012 , vol. 382, # 1 p. 35 - 42

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Citation Number: 4

Abstract

(2-(4-(Benzothiazole) phenyl) carbamoylmethyl) iminodiacetic acid (ZL-5) was synthesized and then its three metal complexes were prepared with structures determined by 1H NMR or X-ray. In all complexes, ZL-5 is deprotonated to generate the neutral complex unit and acts as a tetradentate ligand, providing iminodiacetic N atom and three O atoms to bond with metal ions. Meantime we studied on the interaction of complexes with DNA by ultraviolet ...