Tetrakis (pyridine) silver (II) Peroxodisulfate,(Ag (py) 4) S2O8, a Reagent for the Oxidative Transformations.

…, P Salehi, I Mohammadpour-Baltork

Index: Firouzabadi, Habib; Salehi, Peyman; Mohammadpour-Baltork, Iraj Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 10 p. 2878 - 2880

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Citation Number: 24

Abstract

Tetrakis (pyridine) silver (II) peroxodisulfate oxidizes aromatic aldehydes to carboxylic acids, benzylic alcohols to carbonyl compounds, aromatic thiols, and allylaryl thioethers to arylsulfonic acids and benzylic carbon–hydrogen bonds to carbonyl groups. α- Hydroxycarboxylic acids and phenylacetic acids are decarboxylated to produce carbonyl compounds. Dibenzyl ether and its sulfur analogue are converted to their corresponding ...