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Tetrakis (pyridine) silver (II) Peroxodisulfate,(Ag (py) 4) S2O8, a Reagent for the Oxidative Transformations.

…, P Salehi, I Mohammadpour-Baltork

文献索引:Firouzabadi, Habib; Salehi, Peyman; Mohammadpour-Baltork, Iraj Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 10 p. 2878 - 2880

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被引用次数: 24

摘要

Tetrakis (pyridine) silver (II) peroxodisulfate oxidizes aromatic aldehydes to carboxylic acids, benzylic alcohols to carbonyl compounds, aromatic thiols, and allylaryl thioethers to arylsulfonic acids and benzylic carbon–hydrogen bonds to carbonyl groups. α- Hydroxycarboxylic acids and phenylacetic acids are decarboxylated to produce carbonyl compounds. Dibenzyl ether and its sulfur analogue are converted to their corresponding ...