DEPROTECTION OF 1, 1-DIACETATES WITH [NO+⋅ CROWN⋅ H (NO3) 2−]

…, MH Zebarjadian, I Mohammadpoor-Baltork…

Index: Zolfigol, Mohammad Ali; Zebarjadian, Mohammad Hassan; Mohammadpoor-Baltork, Iraj; Shamsipur, Mojtaba Synthetic Communications, 2002 , vol. 32, # 18 p. 2803 - 2808

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Citation Number: 22

Abstract

ABSTRACT An ionic complex has been obtained from N2O4 in the presence of the macrocyclic polyether 18-crown-6. This crystalline compound was used as an effective deprotecting agent for the conversion of 1, 1-diacetates to their corresponding aldehydes at room temperature with quantitative yields.