Hydride as a Leaving Group in the Reaction of Pinacolborane with Halides under Ambient Grignard and Barbier Conditions. One-Pot Synthesis of Alkyl, Aryl, …

JW Clary, TJ Rettenmaier, R Snelling…

Index: Journal of Organic Chemistry, , vol. 76, # 23 p. 9602 - 9610

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Citation Number: 52

Abstract

... The Journal of Organic Chemistry. ... J. Org. Chem. ... This reaction also can be carried out under Barbier conditions, where the neat PinBH is added to the flask prior to the in situ formation of Grignard reagent from the corresponding organic halide and magnesium metal. ...