Hydrosilylation Of (Hetero) aromatic Aldimines in the Presence of a Pd (I) Complex

…, L Golomba, M Fleisher, J Popelis, S Grinberga…

Index: Iovel; Golomba; Fleisher; Popelis; Grinberga; Lukevics Chemistry of Heterocyclic Compounds, 2004 , vol. 40, # 6 p. 701 - 714

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Citation Number: 10

Abstract

Abstract The reaction of triethylsilane with heterocyclic and aromatic azomethines, catalyzed by the [Pd (allyl) Cl] 2 complex, was studied. It was found that the reaction is affected by the nature of the functional groups in the aza and methine parts of the aldimine molecules, which were produced by the condensation of furan, thiophene, and benzene aldehydes with aniline and its derivatives. The reactivity of a series of imines is compared with their ...