Journal of the American Chemical Society

Acetylenic Silicon Derivatives*

KC Frisch, RB Young

Index: Frisch; Young Journal of the American Chemical Society, 1952 , vol. 74, p. 4853,4855

Full Text: HTML

Citation Number: 53

Abstract

Hexaethynyldisiloxane [(HC= C), Si], O was also prepared by the same investigators by treating ethynylmagnesium bromide with silicon tetrachloride and hydrolyzing the reaction product. Hexaethynyldisiloxane also decomposes in cold water, yielding acetylene and silica, confirming apparently the labile behavior of the carbonsilicon bond in which one of the carbon atoms of the triple bond is linked to silicon. Boldebuck2 in a recent patent ...