Journal of the American Chemical Society

Acetylenic Silicon Derivatives*

KC Frisch, RB Young

文献索引：Frisch; Young Journal of the American Chemical Society, 1952 , vol. 74, p. 4853,4855

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被引用次数: 53

摘要

Hexaethynyldisiloxane [(HC= C), Si], O was also prepared by the same investigators by treating ethynylmagnesium bromide with silicon tetrachloride and hydrolyzing the reaction product. Hexaethynyldisiloxane also decomposes in cold water, yielding acetylene and silica, confirming apparently the labile behavior of the carbonsilicon bond in which one of the carbon atoms of the triple bond is linked to silicon. Boldebuck2 in a recent patent ...