Organic & biomolecular chemistry

Nickel-catalyzed triarylamine synthesis: synthetic and mechanistic aspects

XL Li, W Wu, XH Fan, LM Yang

Index: Li, Xin-Le; Wu, Wei; Fan, Xin-Heng; Yang, Lian-Ming Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1232 - 1236

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Citation Number: 4

Abstract

An improved protocol was described for the amination of chloroarenes with diarylamines under NiCl2 (PCy3) 2 catalysis in the presence of a Grignard reagent as base. This method fully suits bromo-/iodoarene substrates as well, and even is expanded to certain aryl