The Journal of Organic Chemistry

Preparation and Some Reactions of Thiobis-N-(trifluoromethyl) amines1

TE STEVENS

Index: Stevens,T.E. Journal of Organic Chemistry, 1961 , vol. 26, p. 3451 - 3457

Full Text: HTML

Citation Number: 3

Abstract

The fluorination of aryl and alkyl isothiocyanates with iodine pentafluoride in pyridine solution has been found to produce thiobis-N-substituted iV-(trifluoromethy1) amines. The preparation and some of the reactions of these novel compounds are discussed. A unique rearrangement of a thioi) isaniinc to a diphenyl sulfide is reported.

 Related Synthetic Route
1,3-bis-(4-chloro-phenyl)-1,3-bis-trifluoromethyl-diazathiane Structure

1427-93-6

1,3-bis-(4-chlo...

~%

1,3-bis-(4-Chlorophenyl)urea Structure

1219-99-4

1,3-bis-(4-Chlo...

1,3-diphenyl-1,3-bis-trifluoromethyl-diazathiane Structure

444-55-3

1,3-diphenyl-1,...

Sodium ethoxide Structure

141-52-6

Sodium ethoxide

~%

1,1-diethoxy-N-phenyl-methanimine Structure

6263-08-7

1,1-diethoxy-N-...

1,3-bis-(4-bromo-phenyl)-1,3-bis-trifluoromethyl-diazathiane Structure

2802-86-0

1,3-bis-(4-brom...

~%

1,3-bis(4-bromophenyl)urea Structure

6341-55-5

1,3-bis(4-bromo...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved