Journal of fluorine chemistry

Reaction of alkyl 2-chloro-1, 1, 2-irifluoroethyl ethers with lewis acids

M Hudlicky

Index: Hudlicky, Milos Journal of Fluorine Chemistry, 1985 , vol. 29, p. 349 - 354

Full Text: HTML

Citation Number: 7

Abstract

Abstract Ethyl 2-chloro-1, 1, 2-trifluoroethyl ether heated with boron trifluoride etherate gave ethyl fluoride and chlorofluoroacetyl fluoride. When heated with aluminum chloride, it afforded a mixture of ethyl fluoride, ethyl chloride, chlorofluoroacetyl fluoride, and

~44%

~0%

Detail

~47%

~58%

Detail

~31%

Detail

~30%

Detail

~2%

Detail

Vibrational Level Populations of Hydrogen Fluoride Produced ...

[Ishikawa; Arai Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 8 p. 2040 - 2045]

Comparative studies in the 19 F and 1 H NMR chemical shifts ...

[Tanuma; Ohnishi; Okamoto; Morikawa Journal of Fluorine Chemistry, 1996 , vol. 76, # 1 p. 45 - 48]

… and 2-(Dialkylamino)-1, 3-dimethylimidazolinium Trimethyld...

[Tamura, Masanori; Takubo, Seij; Quan, Heng-Dao; Sekiya, Akira Synlett, 2000 , # 3 p. 343 - 344]

Electrophilic reactions at single bonds. 18. Heterogeneous g...

[Olah, George A.; Felberg, Jeff D.; Lammertsma, Koop Journal of the American Chemical Society, 1983 , vol. 105, # 21 p. 6529 - 6531]