Ambident Reactivity of Chloro (dialkylamino)(diphenylphosphinoyl) methanes

VP Morgalyuk, TV Strelkova, EE Nifant'ev

Index: Morgalyuk, Vasilii Petrovich; Strelkova, Tat'Yana Vladimirovna; Nifant'Ev, Eduard Eugenievich Bulletin of the Chemical Society of Japan, 2012 , vol. 85, # 1 p. 93 - 100

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Citation Number: 5

Abstract

The chemical properties of chloro (dialkylamino)(diphenylphosphinoyl) methanes have been studied using the simplest compound of this series, chloro (dimethylamino)( diphenylphosphinoyl) methane, as an example. Chloro (dimethylamino)( diphenylphosphinoyl) methane shows ambident reactivity when reacting with electrophiles and nucleophiles depending on coreactant nature, it behaves as either electrophilic ...