Ambident Reactivity of Chloro (dialkylamino)(diphenylphosphinoyl) methanes

VP Morgalyuk, TV Strelkova, EE Nifant'ev

文献索引：Morgalyuk, Vasilii Petrovich; Strelkova, Tat'Yana Vladimirovna; Nifant'Ev, Eduard Eugenievich Bulletin of the Chemical Society of Japan, 2012 , vol. 85, # 1 p. 93 - 100

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被引用次数: 5

摘要

The chemical properties of chloro (dialkylamino)(diphenylphosphinoyl) methanes have been studied using the simplest compound of this series, chloro (dimethylamino)( diphenylphosphinoyl) methane, as an example. Chloro (dimethylamino)( diphenylphosphinoyl) methane shows ambident reactivity when reacting with electrophiles and nucleophiles depending on coreactant nature, it behaves as either electrophilic ...